#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-04-26 13:44:52 +0300 (Thu, 26 Apr 2018) $ #$Revision: 554 $ #$URL: svn://172.16.1.111/rod/cif/8/10/00/8100010.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_8100010 loop_ _publ_author_name 'Ferraris, G.' 'Gula, A.' 'Ivaldi, G.' 'Nespolo, M.' 'Raade, G.' _publ_section_title ; Crystal structure of kristiansenite: a case of class IIB twinning by metric merohedry Locality: amazonite pegmatite, Heftetjern, Tordal, Telemark, Norway ; _journal_name_full 'Zeitschrift fur Kristallographie' _journal_page_first 442 _journal_page_last 448 _journal_volume 216 _journal_year 2001 _chemical_compound_source R090022 _chemical_formula_sum 'Ca4 Fe0.41 H2 O28 Sc1.52 Si8 Sn2.07' _chemical_name_mineral Kristiansenite _space_group_IT_number 1 _symmetry_space_group_name_Hall 'P 1 (1/2*x+1/2*y,1/2*x-1/2*y,-z)' _symmetry_space_group_name_H-M 'C 1' _cell_angle_alpha 90.01 _cell_angle_beta 109.10 _cell_angle_gamma 90.00 _cell_length_a 10.028 _cell_length_b 8.408 _cell_length_c 13.339 _cell_volume 1062.768 _exptl_crystal_density_diffrn 3.662 _cod_original_formula_sum 'Ca4 Sn2.07 Fe.41 Sc1.52 Si8 O28 H2' _cod_database_code 9011523 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type helium-neon _raman_measurement_device.excitation_laser_wavelength 780 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 12 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R090022.rod _rod_data_source.block 3500000 _rod_database.code 8100010 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9011523 COD http://www.crystallography.net/cod/9011523.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 102.5014 0.0000000E+00 102.9835 9.9120997E-02 103.4656 0.7991940 103.9478 3.036346 104.4299 6.206329 104.9120 9.093597 105.3941 11.67557 105.8762 14.30811 106.3583 14.94003 106.8405 12.77362 107.3226 10.07050 107.8047 7.231750 108.2868 4.372131 108.7689 2.344971 109.2510 2.365051 109.7332 4.656250 110.2153 8.399261 110.6974 13.62711 111.1795 20.04361 111.6616 27.63617 112.1437 36.86102 112.6259 46.16049 113.1080 53.89685 113.5901 60.15323 114.0722 65.68802 114.5543 71.00418 115.0364 76.38928 115.5185 81.41187 116.0007 85.85065 116.4828 90.26215 116.9649 94.83466 117.4470 99.99966 117.9291 106.4796 118.4112 114.1627 118.8934 121.7520 119.3755 129.1104 119.8576 137.1801 120.3397 144.2754 120.8218 149.7220 121.3039 153.8942 121.7861 156.4245 122.2682 156.6082 122.7503 155.5457 123.2324 150.8716 123.7145 141.0768 124.1966 127.9228 124.6788 113.7390 125.1609 99.49861 125.6430 85.34418 126.1251 72.54971 126.6072 60.50403 127.0893 49.92648 127.5715 41.47276 128.0536 34.91428 128.5357 29.23221 129.0178 23.77132 129.4999 18.62700 129.9821 13.97064 130.4642 9.736481 130.9463 5.998016 131.4284 2.875076 131.9105 0.4358370 132.3926 1.595657 132.8748 3.512878 133.3569 5.209747 133.8390 6.327179 134.3211 6.597275 134.8032 6.156448 135.2853 5.448349 135.7674 4.401062 136.2496 3.149826 136.7317 1.735901 137.2138 0.1964720 137.6959 1.386505 138.1780 3.201447 138.6601 5.379227 139.1423 6.385437 139.6244 4.332138 140.1065 2.635529 140.5886 2.554672 141.0707 4.151825 141.5528 6.798309 142.0350 9.807053 142.5171 13.25777 142.9992 16.95041 143.4813 20.56726 143.9634 24.55185 144.4455 29.43045 144.9277 35.24332 145.4098 41.44501 145.8919 47.16252 146.3740 52.19785 146.8561 57.03438 147.3382 60.97238 147.8204 64.95618 148.3025 70.10693 148.7846 76.82843 149.2667 84.89200 149.7488 93.93845 150.2309 103.4770 150.7131 114.7712 151.1952 128.3490 151.6773 144.0847 152.1594 161.5089 152.6415 181.0876 153.1236 201.9084 153.6058 223.1042 154.0879 245.4598 154.5700 265.5184 155.0521 281.1421 155.5342 292.3613 156.0163 298.0492 156.4985 295.3082 156.9806 287.4820 157.4627 276.1107 157.9448 261.1028 158.4269 244.4934 158.9090 228.7629 159.3912 213.3834 159.8733 200.6049 160.3554 191.6782 160.8375 185.0947 161.3196 180.1596 161.8017 176.6000 162.2839 174.5255 162.7660 174.3723 163.2481 177.5125 163.7302 180.9536 164.2123 184.1844 164.6944 187.4578 165.1766 191.0638 165.6587 195.1785 166.1408 199.7642 166.6229 204.8098 167.1050 210.1959 167.5871 216.2068 168.0693 222.7226 168.5514 229.9302 169.0335 237.9995 169.5156 246.8342 169.9977 256.6923 170.4798 269.7470 170.9620 285.7056 171.4441 304.2842 171.9262 325.9040 172.4083 350.2088 172.8904 376.1010 173.3725 402.8681 173.8547 430.5432 174.3368 459.0354 174.8189 490.7881 175.3010 521.8484 175.7831 550.9238 176.2652 578.1911 176.7474 598.3858 177.2295 606.9918 177.7116 605.0771 178.1937 594.0919 178.6758 570.4135 179.1579 539.1602 179.6401 506.2787 180.1222 470.5871 180.6043 437.2708 181.0864 409.5450 181.5685 386.1805 182.0506 366.1133 182.5328 348.7415 183.0149 334.3232 183.4970 323.6782 183.9791 317.6195 184.4612 314.7246 184.9433 314.5444 185.4255 316.4370 185.9076 319.4353 186.3897 323.1182 186.8718 327.4138 187.3539 331.6350 187.8360 335.9490 188.3182 339.9828 188.8003 344.2885 189.2824 348.2397 189.7645 350.7794 190.2466 350.8489 190.7287 348.2894 191.2109 345.3524 191.6930 341.5461 192.1751 337.9400 192.6572 334.3143 193.1393 331.1422 193.6214 329.4705 194.1036 330.3718 194.5857 334.2347 195.0678 337.5260 195.5499 340.9787 196.0320 343.3640 196.5141 344.8473 196.9963 344.9421 197.4784 342.3375 197.9605 335.9837 198.4426 325.5156 198.9247 311.6774 199.4068 292.9066 199.8890 272.3596 200.3711 251.3885 200.8532 230.2731 201.3353 209.8152 201.8174 190.3487 202.2995 172.0565 202.7817 156.2802 203.2638 143.7437 203.7459 133.3283 204.2280 123.9860 204.7101 115.5740 205.1922 108.6662 205.6744 104.1267 206.1565 101.6340 206.6386 100.0375 207.1207 99.35062 207.6028 99.39337 208.0849 100.0956 208.5671 101.6388 209.0492 103.1154 209.5313 103.9016 210.0134 104.1229 210.4955 103.8426 210.9776 102.9821 211.4598 101.5157 211.9419 99.38052 212.4240 96.17725 212.9061 93.36917 213.3882 91.51468 213.8703 90.60254 214.3525 90.73975 214.8346 92.02695 215.3167 94.40732 215.7988 97.74377 216.2809 102.5257 216.7630 107.5954 217.2451 112.1856 217.7273 116.6794 218.2094 121.7602 218.6915 127.8688 219.1736 134.9070 219.6557 142.2535 220.1378 149.9926 220.6200 157.9478 221.1021 165.5980 221.5842 173.4306 222.0663 182.4024 222.5484 193.3176 223.0305 205.8960 223.5127 217.4770 223.9948 228.7119 224.4769 237.9149 224.9590 244.9237 225.4411 249.6713 225.9232 251.9936 226.4054 251.6964 226.8875 248.9340 227.3696 245.3593 227.8517 240.6016 228.3338 235.4066 228.8159 229.6051 229.2981 223.4933 229.7802 217.7151 230.2623 212.7496 230.7444 208.4120 231.2265 202.6736 231.7086 195.4920 232.1908 187.1207 232.6729 176.7922 233.1550 165.3016 233.6371 154.1945 234.1192 144.5203 234.6013 135.9341 235.0835 125.7957 235.5656 112.3268 236.0477 99.48700 236.5298 88.38559 237.0119 78.80969 237.4940 70.10486 237.9762 61.94037 238.4583 54.37552 238.9404 47.68027 239.4225 42.02448 239.9046 36.85782 240.3867 32.08447 240.8689 27.68085 241.3510 23.55292 241.8331 19.54810 242.3152 15.93839 242.7973 13.49069 243.2794 12.77051 243.7616 12.09659 244.2437 10.76697 244.7258 8.925873 245.2079 7.037811 245.6900 5.376648 246.1721 3.663177 246.6543 1.184296 247.1364 2.532532 247.6185 5.680664 248.1006 7.104340 248.5827 7.149689 249.0648 7.057556 249.5470 7.202057 250.0291 7.427826 250.5112 7.556732 250.9933 7.620941 251.4754 7.456635 251.9576 6.901184 252.4397 6.019501 252.9218 5.088898 253.4039 4.247742 253.8860 3.284271 254.3681 1.835602 254.8503 0.1023250 255.3324 1.736694 255.8145 2.315338 256.2966 2.071320 256.7787 2.272919 257.2608 3.560852 257.7430 4.770294 258.2251 4.876312 258.7072 4.011627 259.1893 3.047760 259.6714 2.612549 260.1535 2.585449 260.6357 2.269592 261.1178 1.498322 261.5999 0.5484310 262.0820 0.5225220 262.5641 1.632843 263.0462 2.538147 263.5284 2.946533 264.0105 2.960510 264.4926 3.223785 264.9747 3.926544 265.4568 4.613861 265.9389 5.072083 266.4211 5.357513 266.9032 5.620270 267.3853 6.146515 267.8674 6.712708 268.3495 6.226715 268.8316 3.906403 269.3138 1.677216 269.7959 0.4227600 270.2780 0.3249510 270.7601 1.224518 271.2422 2.566437 271.7243 4.358307 272.2065 6.579376 272.6886 9.059998 273.1707 12.33859 273.6528 17.04153 274.1349 22.31021 274.6170 27.00400 275.0992 30.56448 275.5813 33.60376 276.0634 37.68631 276.5455 43.53961 277.0276 49.12393 277.5097 53.89005 277.9919 58.35730 278.4740 63.16269 278.9561 68.54785 279.4382 73.89789 279.9203 77.97324 280.4024 79.90689 280.8846 82.35605 281.3667 85.59811 281.8488 89.35034 282.3309 93.61270 282.8130 98.30560 283.2951 102.9935 283.7773 106.9048 284.2594 109.4328 284.7415 112.7149 285.2236 117.0735 285.7057 121.8767 286.1878 127.1013 286.6700 132.5338 287.1521 137.6039 287.6342 141.5533 288.1163 143.9467 288.5984 146.8173 289.0805 150.2045 289.5627 153.9655 290.0448 158.3606 290.5269 163.1672 291.0090 167.7766 291.4911 171.6948 291.9732 174.9258 292.4554 177.2971 292.9375 179.5553 293.4196 180.2433 293.9017 178.6189 294.3838 175.0086 294.8659 170.0512 295.3481 164.1036 295.8302 157.2241 296.3123 150.5321 296.7944 145.2127 297.2765 138.7618 297.7586 130.0382 298.2408 120.0023 298.7229 110.0393 299.2050 100.9279 299.6871 92.59875 300.1692 84.83630 300.6513 77.19031 301.1335 70.86844 301.6156 66.52682 302.0977 63.37119 302.5798 60.53732 303.0619 57.69629 303.5440 55.09082 304.0262 53.24219 304.5083 53.01019 304.9904 52.16095 305.4725 50.31793 305.9546 48.15103 306.4367 46.11850 306.9189 44.35706 307.4010 42.84335 307.8831 41.58234 308.3652 40.71072 308.8473 39.76566 309.3294 38.69870 309.8116 37.64194 310.2937 36.54535 310.7758 35.48904 311.2579 34.75333 311.7400 34.67041 312.2221 35.36667 312.7043 35.95898 313.1864 36.62695 313.6685 36.92996 314.1506 36.27832 314.6327 35.08362 315.1148 34.30887 315.5970 34.68597 316.0791 36.13602 316.5612 37.57806 317.0433 38.25665 317.5254 39.78189 318.0075 43.04227 318.4897 47.25613 318.9718 51.14200 319.4539 54.01303 319.9360 56.35233 320.4181 59.82672 320.9002 65.83356 321.3824 71.26767 321.8645 75.12790 322.3466 78.75259 322.8287 83.76328 323.3108 90.58749 323.7929 98.07571 324.2751 104.0884 324.7572 107.2740 325.2393 111.6044 325.7214 117.7317 326.2035 124.4161 326.6856 131.0091 327.1678 137.3355 327.6499 143.5170 328.1320 149.6949 328.6141 155.7871 329.0962 162.3120 329.5783 169.2740 330.0605 176.5992 330.5426 184.7861 331.0247 193.3868 331.5068 201.2300 331.9889 207.3291 332.4710 211.8695 332.9532 217.3232 333.4353 224.6383 333.9174 232.0463 334.3995 239.3138 334.8816 246.3795 335.3637 253.2252 335.8459 259.8068 336.3280 266.1287 336.8101 272.0756 337.2922 277.6464 337.7743 282.7833 338.2564 286.7745 338.7386 290.6890 339.2206 295.6464 339.7028 301.8825 340.1849 308.5017 340.6670 314.3138 341.1491 319.5033 341.6312 323.6078 342.1133 325.7646 342.5955 327.4876 343.0776 329.9986 343.5597 333.0368 344.0418 335.2104 344.5239 335.1421 345.0060 332.7198 345.4882 329.8320 345.9703 326.4971 346.4524 322.7419 346.9345 317.9390 347.4166 312.7913 347.8987 308.4293 348.3809 305.4968 348.8630 303.9278 349.3451 303.6667 349.8272 306.0395 350.3093 307.6588 350.7914 307.0576 351.2736 305.8689 351.7557 305.4394 352.2378 306.2516 352.7199 308.5416 353.2020 313.1371 353.6841 321.1491 354.1663 328.0574 354.6484 332.5790 355.1305 336.5013 355.6126 340.4180 356.0947 344.5849 356.5768 349.4330 357.0590 355.4704 357.5411 362.6911 358.0232 370.3912 358.5053 379.1062 358.9874 387.7095 359.4695 395.0686 359.9517 401.9629 360.4338 409.9898 360.9159 420.2838 361.3980 432.2242 361.8801 444.2102 362.3622 456.4839 362.8444 468.1115 363.3265 478.4422 363.8086 488.1720 364.2907 498.1790 364.7728 508.8911 365.2549 519.2523 365.7371 528.4413 366.2192 536.6902 366.7013 541.9257 367.1834 543.2485 367.6655 541.3907 368.1476 537.1309 368.6298 530.4437 369.1119 520.6896 369.5940 507.3150 370.0761 490.4758 370.5582 470.6024 371.0403 446.5713 371.5225 421.5375 372.0046 396.9549 372.4867 373.0641 372.9688 350.2350 373.4509 329.0398 373.9330 308.8536 374.4152 288.4778 374.8973 267.7969 375.3794 248.5830 375.8615 232.3527 376.3436 218.0689 376.8257 203.9639 377.3079 189.6264 377.7900 176.0577 378.2721 164.2402 378.7542 153.8744 379.2363 143.6907 379.7184 133.2916 380.2006 122.9455 380.6827 112.6467 381.1648 102.3780 381.6469 93.31017 382.1290 86.51729 382.6111 80.81714 383.0933 74.60654 383.5754 67.66190 384.0575 60.50027 384.5396 53.03069 385.0217 45.58844 385.5038 39.76956 385.9860 37.16086 386.4681 34.83255 386.9502 30.70042 387.4323 25.28841 387.9144 20.46924 388.3965 17.26259 388.8787 15.02634 389.3608 12.04654 389.8429 7.853806 390.3250 4.003845 390.8071 0.8399810 391.2892 1.831299 391.7714 4.192017 392.2535 6.289139 392.7356 8.190933 393.2177 9.957550 393.6998 11.58234 394.1819 13.05681 394.6641 14.64442 395.1462 15.87648 395.6283 16.42921 396.1104 16.38123 396.5925 15.92610 397.0746 15.12706 397.5568 14.11259 398.0389 13.59467 398.5210 14.66422 399.0031 14.91025 399.4852 13.79225 399.9673 11.84407 400.4495 9.562180 400.9316 7.132248 401.4137 4.556107 401.8958 1.823425 402.3779 1.126587 402.8600 4.074219 403.3422 6.706451 403.8243 9.629074 404.3064 13.11263 404.7885 17.16505 405.2706 21.72662 405.7527 26.77383 406.2349 32.27437 406.7170 37.72357 407.1991 42.78152 407.6812 48.26462 408.1633 54.58322 408.6454 61.27800 409.1276 67.72931 409.6097 73.68301 410.0918 79.74545 410.5739 86.91139 411.0560 95.29962 411.5381 104.0116 412.0203 112.9020 412.5024 122.0999 412.9845 131.7872 413.4666 141.8515 413.9487 151.9043 414.4308 161.5689 414.9130 170.9595 415.3951 180.3982 415.8772 189.6628 416.3593 199.5286 416.8414 211.0449 417.3235 223.2504 417.8057 234.7815 418.2878 245.0093 418.7699 255.1085 419.2520 266.2697 419.7341 278.4213 420.2162 290.8568 420.6984 303.1250 421.1805 315.8607 421.6626 329.6414 422.1447 344.5071 422.6268 360.2684 423.1089 378.2570 423.5911 396.4760 424.0732 412.2578 424.5553 425.2451 425.0374 436.8059 425.5195 448.2153 426.0016 458.9206 426.4838 466.5006 426.9659 471.8083 427.4480 473.2605 427.9301 469.4520 428.4122 461.2883 428.8943 450.3471 429.3765 437.0750 429.8586 422.1709 430.3407 406.7284 430.8228 390.1335 431.3049 374.3551 431.7870 359.8550 432.2692 345.9174 432.7513 331.6079 433.2334 317.2414 433.7155 304.1273 434.1976 293.4979 434.6797 285.2032 435.1619 276.8258 435.6440 267.7076 436.1261 259.2497 436.6082 251.6038 437.0903 244.7788 437.5724 238.8503 438.0546 233.8355 438.5367 229.3862 439.0188 224.9553 439.5009 220.4505 439.9830 216.2708 440.4651 211.5238 440.9473 208.1113 441.4294 207.6028 441.9115 209.1792 442.3936 210.6331 442.8757 210.4131 443.3578 209.1882 443.8400 208.9783 444.3221 209.9474 444.8042 211.1877 445.2863 212.3200 445.7684 213.5909 446.2505 215.0819 446.7327 216.7127 447.2148 218.9108 447.6969 222.7113 448.1790 227.5620 448.6611 230.5636 449.1432 230.5234 449.6254 230.0632 450.1075 231.5003 450.5896 234.4471 451.0717 237.7247 451.5538 241.9147 452.0359 245.6689 452.5181 247.0427 453.0002 246.4435 453.4823 246.6140 453.9644 248.9680 454.4465 252.6994 454.9286 256.1019 455.4108 259.2957 455.8929 261.9336 456.3750 263.5372 456.8571 264.6602 457.3392 266.1585 457.8214 268.1011 458.3035 269.7136 458.7856 270.4078 459.2677 270.1965 459.7498 268.5427 460.2319 265.2803 460.7141 261.0384 461.1962 255.4259 461.6783 249.0512 462.1604 242.8769 462.6425 237.2359 463.1246 231.4802 463.6068 224.4293 464.0889 215.3893 464.5710 206.9997 465.0531 199.0141 465.5352 191.8733 466.0173 185.9164 466.4995 180.9776 466.9816 176.5487 467.4637 172.1670 467.9458 168.2122 468.4279 166.0123 468.9100 166.0945 469.3922 166.5639 469.8743 167.0252 470.3564 167.5503 470.8385 168.1868 471.3206 168.9430 471.8027 169.8339 472.2849 171.1151 472.7670 172.5788 473.2491 173.4652 473.7312 173.7573 474.2133 173.3140 474.6954 171.7620 475.1776 169.3880 475.6597 166.8039 476.1418 164.1457 476.6239 161.2626 477.1060 158.2001 477.5881 154.8579 478.0703 150.6902 478.5524 145.4023 479.0345 139.7726 479.5166 134.8474 479.9987 130.5863 480.4808 127.3496 480.9630 125.6135 481.4451 124.5484 481.9272 123.3161 482.4093 122.2140 482.8914 122.3066 483.3735 124.2781 483.8557 127.7957 484.3378 131.6838 484.8199 135.9694 485.3020 140.6285 485.7841 145.2497 486.2662 150.5200 486.7484 157.4930 487.2305 165.9383 487.7126 174.3166 488.1947 181.7534 488.6768 188.0982 489.1589 191.1489 489.6411 190.4774 490.1232 186.9067 490.6053 181.1486 491.0874 172.9275 491.5695 161.5578 492.0516 146.7552 492.5338 130.3132 493.0159 113.6038 493.4980 96.68945 493.9801 80.61230 494.4622 65.29968 494.9443 51.30609 495.4265 39.30331 495.9086 28.96881 496.3907 19.90448 496.8728 12.15094 497.3549 5.491394 497.8370 0.1458130 498.3192 4.800095 498.8013 8.456833 499.2834 10.93280 499.7655 12.88312 500.2476 15.50426 500.7297 19.26152 501.2119 21.98607 501.6940 23.14818 502.1761 23.56583 502.6582 23.84682 503.1403 23.91919 503.6224 23.38696 504.1045 21.99991 504.5866 19.82237 505.0688 17.04910 505.5509 13.10663 506.0330 9.430450 506.5151 6.511002 506.9972 3.541199 507.4793 0.1059570 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561.4764 230.5305 561.9586 222.4124 562.4407 215.9745 562.9228 210.3974 563.4049 205.8985 563.8870 201.8085 564.3691 197.3866 564.8513 192.6895 565.3334 188.1258 565.8155 183.7605 566.2976 179.6320 566.7797 175.7789 567.2618 171.9612 567.7440 169.1544 568.2261 168.1317 568.7082 167.4241 569.1903 166.2415 569.6724 164.6709 570.1545 162.9783 570.6367 161.2866 571.1188 159.8318 571.6009 159.0205 572.0830 158.7587 572.5651 160.2529 573.0472 164.4051 573.5294 169.2383 574.0115 173.6546 574.4936 177.9752 574.9757 183.0701 575.4578 189.3666 575.9399 196.5098 576.4221 203.9007 576.9042 211.6344 577.3863 220.6281 577.8684 231.2751 578.3505 242.9583 578.8326 254.9121 579.3148 267.1285 579.7969 279.9038 580.2790 292.9855 580.7611 306.8920 581.2432 321.7130 581.7253 337.6227 582.2075 354.8693 582.6896 373.4341 583.1717 393.8478 583.6538 416.9207 584.1359 442.9793 584.6180 469.5235 585.1002 496.1622 585.5823 524.0938 586.0643 554.2177 586.5464 585.6510 587.0286 617.6672 587.5107 650.3223 587.9928 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