#\#CIF_2.0 #------------------------------------------------------------------------------ #$Date: 2018-06-07 10:40:57 +0300 (Thu, 07 Jun 2018) $ #$Revision: 917 $ #$URL: svn://172.16.1.111/rod/cif/8/10/00/8100025.rod $ #------------------------------------------------------------------------------ # # This file is available in the Raman Open Database (ROD), # http://solsa.crystallography.net/rod/ # # All data on this site have been placed in the public domain by the # contributors. # data_8100025 loop_ _publ_author_name 'Newnham, R. E.' 'de Haan, Y. M.' _publ_section_title ; Refinement of the alpha Al2O3, Ti2O3, V2O3 and Cr2O3 structures Locality: synthetic ; _journal_name_full 'Zeitschrift fur Kristallographie' _journal_page_first 235 _journal_page_last 237 _journal_volume 117 _journal_year 1962 _chemical_compound_source R040096 _chemical_formula_sum 'Al2 O3' _chemical_name_mineral Corundum _space_group_IT_number 167 _symmetry_space_group_name_Hall '-R 3 2"c' _symmetry_space_group_name_H-M 'R -3 c :H' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 120 _cell_length_a 4.7589 _cell_length_b 4.7589 _cell_length_c 12.991 _cell_volume 254.792 _exptl_crystal_density_diffrn 3.987 _cod_original_sg_symbol_H-M 'R -3 c' _cod_database_code 9008081 _raman_determination_method experimental _raman_measurement_device.location 'Arizona University' _raman_measurement_device.company 'Thermo Scientific' _raman_measurement_device.model 'Nicolet Almega XR' _raman_measurement_device.optics_type microscope _raman_measurement_device.microscope_system dispersive _raman_measurement_device.microscope_objective_magnification 50 _raman_measurement_device.microscope_numerical_aperture 0.5 _raman_measurement_device.excitation_laser_type other _raman_measurement_device.excitation_laser_wavelength 532 _raman_measurement_device.configuration simple _raman_measurement_device.resolution 4 _raman_measurement_device.power_on_sample 15 _raman_measurement_device.direction_polarization unoriented _raman_measurement_device.spot_size 1 _raman_measurement_device.diffraction_grating 400 _raman_measurement.environment Air _raman_measurement.environment_details ; The sample was measured in air. ; _raman_measurement.temperature 300 _raman_measurement.pressure 100 _raman_measurement.background_subtraction no _raman_measurement.background_subtraction_details ; No background subtraction method was applied. ; _raman_measurement.baseline_correction no _raman_measurement.baseline_correction_details ; No baseline correction method was applied. ; _raman_measurement.integration_time 10 _rod_data_source.file R040096.rod _rod_data_source.block 3500000 _rod_database.code 8100025 loop_ _raman_complementary.id _raman_complementary.method 1 XRD loop_ _raman_measurement_device_calibration.id _raman_measurement_device_calibration.standard 1 neon_lamp loop_ _rod_related_entry.id _rod_related_entry.code _rod_related_entry.database _rod_related_entry.uri _rod_related_entry.description 1 9008081 COD http://www.crystallography.net/cod/9008081.html ; XRD analysis data was done. ; loop_ _raman_spectrum.raman_shift _raman_spectrum.intensity 147.6079 0.0000000E+00 148.0901 5.562500 148.5722 10.19238 149.0543 12.61133 149.5364 8.908203 150.0185 4.577148 150.5006 1.544922 150.9828 0.4414060 151.4649 8.311523 151.9470 24.35742 152.4291 45.79785 152.9112 83.50684 153.3933 120.7510 153.8755 146.4023 154.3576 149.7236 154.8397 150.5127 155.3218 152.0488 155.8039 154.3018 156.2860 157.8652 156.7682 170.6006 157.2503 182.5898 157.7324 187.8516 158.2145 156.8252 158.6966 121.4541 159.1787 98.94824 159.6609 80.54199 160.1430 99.74121 160.6251 207.6689 161.1072 361.1631 161.5893 467.5811 162.0714 480.3438 162.5536 442.2422 163.0357 379.0527 163.5178 263.9980 163.9999 163.5781 164.4820 119.9023 164.9641 124.5078 165.4463 130.3066 165.9284 113.6445 166.4105 83.96387 166.8926 53.74023 167.3747 16.83301 167.8568 9.709961 168.3390 9.775391 168.8211 17.86328 169.3032 49.25000 169.7853 75.41309 170.2674 88.29004 170.7495 92.82617 171.2317 85.75293 171.7138 71.74219 172.1959 54.62695 172.6780 33.02051 173.1601 17.80762 173.6422 22.15820 174.1244 40.25684 174.6065 57.93262 175.0886 72.40430 175.5707 76.08496 176.0528 73.76172 176.5349 59.88770 177.0171 50.65430 177.4992 72.04980 177.9813 119.5879 178.4634 164.2510 178.9455 189.3115 179.4276 194.5439 179.9098 179.1631 180.3919 131.1162 180.8740 79.74414 181.3561 43.80469 181.8382 36.41895 182.3203 40.79102 182.8025 45.66211 183.2846 35.55176 183.7667 30.64746 184.2488 33.09668 184.7309 44.95410 185.2130 80.99023 185.6951 149.3535 186.1773 214.2510 186.6594 220.0537 187.1415 172.1377 187.6236 122.4570 188.1057 97.33203 188.5878 93.87891 189.0700 98.46387 189.5521 114.5957 190.0342 129.5771 190.5163 106.8818 190.9984 44.52539 191.4805 1.681641 191.9627 29.84961 192.4448 130.1357 192.9269 187.3027 193.4090 169.6396 193.8911 104.0049 194.3732 71.94922 194.8554 78.71582 195.3375 98.94727 195.8196 110.0010 196.3017 114.2178 196.7838 112.1221 197.2659 101.8789 197.7481 85.26367 198.2302 69.22363 198.7123 50.40723 199.1944 42.84082 199.6765 79.75684 200.1586 172.1885 200.6408 227.5391 201.1229 193.9121 201.6050 69.58008 202.0871 1.828125 202.5692 9.005859 203.0513 19.80176 203.5335 39.51367 204.0156 49.63965 204.4977 55.55957 204.9798 58.67090 205.4619 59.54785 205.9440 60.11816 206.4262 58.28613 206.9083 57.32129 207.3904 69.02832 207.8725 99.36816 208.3546 125.4902 208.8367 132.1396 209.3189 114.0088 209.8010 98.22656 210.2831 87.32031 210.7652 80.45898 211.2473 75.97266 211.7294 78.54785 212.2116 74.84863 212.6937 47.53809 213.1758 19.79590 213.6579 55.07129 214.1400 37.62695 214.6221 28.31836 215.1043 77.00391 215.5864 111.7988 216.0685 126.1875 216.5506 104.9824 217.0327 23.99902 217.5148 29.99805 217.9970 29.62598 218.4791 29.24512 218.9612 67.31836 219.4433 74.83789 219.9254 70.42871 220.4075 78.92871 220.8897 106.1494 221.3718 133.4600 221.8539 156.5371 222.3360 177.6289 222.8181 182.5156 223.3002 160.8623 223.7824 129.2207 224.2645 120.8408 224.7466 153.6562 225.2287 178.6924 225.7108 172.2363 226.1929 115.1426 226.6750 84.56836 227.1572 86.48145 227.6393 112.5098 228.1214 144.7549 228.6035 194.2041 229.0856 235.3408 229.5677 250.0947 230.0499 222.6660 230.5320 207.2178 231.0141 210.3223 231.4962 227.4355 231.9783 240.7002 232.4604 252.8311 232.9426 256.9971 233.4247 247.3457 233.9068 214.2217 234.3889 187.0850 234.8710 168.8623 235.3531 159.1377 235.8353 155.0898 236.3174 161.7305 236.7995 168.6621 237.2816 167.6064 237.7637 153.6143 238.2458 141.1572 238.7280 130.0596 239.2101 120.5029 239.6922 125.3633 240.1743 163.8359 240.6564 197.7295 241.1385 185.6172 241.6207 84.37598 242.1028 13.22852 242.5849 0.6826170 243.0670 47.09570 243.5491 100.2725 244.0313 168.5352 244.5134 233.7627 244.9955 273.0615 245.4776 271.1934 245.9597 270.5879 246.4418 288.2383 246.9240 333.8867 247.4061 339.2646 247.8882 282.8799 248.3703 202.1299 248.8524 152.1953 249.3345 142.5254 249.8167 145.5518 250.2988 152.8174 250.7809 162.6621 251.2630 167.7197 251.7451 166.2539 252.2272 161.7100 252.7094 160.5488 253.1915 163.6230 253.6736 168.4951 254.1557 173.6250 254.6378 176.5146 255.1199 189.4600 255.6021 226.6602 256.0842 267.3506 256.5663 259.4521 257.0484 164.6172 257.5305 80.00586 258.0126 57.02930 258.4948 126.9639 258.9769 171.9072 259.4590 181.3320 259.9411 164.5918 260.4232 159.9590 260.9053 177.3271 261.3875 193.1855 261.8696 194.5244 262.3517 175.3760 262.8338 159.4209 263.3159 145.2041 263.7980 138.1035 264.2802 151.2510 264.7623 188.4531 265.2444 222.6904 265.7265 244.2217 266.2086 252.4951 266.6907 251.0889 267.1729 231.5918 267.6550 202.9834 268.1371 205.4004 268.6192 252.5566 269.1013 299.4736 269.5834 309.7598 270.0656 272.2031 270.5477 250.4697 271.0298 257.1973 271.5119 282.4326 271.9940 284.1221 272.4761 256.0508 272.9583 224.8213 273.4404 213.9932 273.9225 228.0342 274.4046 238.3838 274.8867 240.6934 275.3688 233.8594 275.8510 224.5908 276.3331 216.5557 276.8152 203.3486 277.2973 175.0371 277.7794 128.1855 278.2615 99.47559 278.7437 100.4189 279.2258 124.3232 279.7079 138.9277 280.1900 141.1133 280.6721 146.1982 281.1542 178.6396 281.6364 240.9619 282.1185 270.6279 282.6006 239.9580 283.0827 169.5117 283.5648 153.7822 284.0469 203.6396 284.5291 251.5615 285.0112 216.5928 285.4933 102.0830 285.9754 16.28613 286.4575 6.939453 286.9396 16.93945 287.4217 40.76855 287.9038 65.49023 288.3860 85.20801 288.8681 91.07129 289.3502 84.34570 289.8323 79.02539 290.3144 78.47949 290.7965 81.79199 291.2787 85.59277 291.7608 89.60938 292.2429 97.45703 292.7250 122.2520 293.2071 158.0762 293.6892 174.1602 294.1714 150.9502 294.6535 106.1035 295.1356 77.89941 295.6177 67.04102 296.0998 61.57617 296.5819 49.69531 297.0641 33.91699 297.5462 22.21777 298.0283 16.85938 298.5104 17.46973 298.9925 27.88086 299.4746 48.01465 299.9568 62.79199 300.4389 53.31836 300.9210 30.38672 301.4031 14.68262 301.8852 14.13379 302.3673 23.92676 302.8495 43.79102 303.3316 72.95703 303.8137 95.83789 304.2958 99.79492 304.7779 88.17773 305.2600 66.59668 305.7422 23.56055 306.2243 19.87500 306.7064 48.56543 307.1885 62.27734 307.6706 51.35156 308.1527 14.26367 308.6349 103.8369 309.1170 173.2949 309.5991 213.7217 310.0812 224.1943 310.5633 188.1963 311.0454 109.0352 311.5276 43.72070 312.0097 44.36230 312.4918 71.34863 312.9739 80.56250 313.4560 27.23438 313.9381 23.89746 314.4203 28.30371 314.9024 10.09375 315.3845 40.04199 315.8666 23.32715 316.3487 6.312500 316.8308 17.94531 317.3130 13.69336 317.7951 49.87207 318.2772 80.23145 318.7593 104.0869 319.2414 114.0928 319.7235 106.4980 320.2057 84.80273 320.6878 51.82812 321.1699 29.46289 321.6520 83.64453 322.1341 74.01465 322.6162 7.859375 323.0984 39.00488 323.5805 23.91992 324.0626 1.611328 324.5447 9.018555 325.0268 110.0830 325.5089 176.3682 325.9911 172.7256 326.4732 106.4131 326.9553 58.13281 327.4374 37.55273 327.9195 32.43555 328.4016 35.43945 328.8838 53.16602 329.3659 70.19531 329.8480 87.33008 330.3301 103.4004 330.8122 112.1211 331.2943 105.2461 331.7765 99.06348 332.2586 103.5225 332.7407 128.3955 333.2228 144.9746 333.7049 139.6221 334.1870 124.4531 334.6692 153.9990 335.1513 255.0273 335.6334 358.7822 336.1155 432.4033 336.5976 483.1758 337.0797 479.0625 337.5619 398.7969 338.0440 270.8975 338.5261 179.7227 339.0082 132.0615 339.4903 100.3750 339.9724 70.58203 340.4546 41.63477 340.9367 21.26953 341.4188 9.771484 341.9009 7.045898 342.3830 18.71973 342.8651 47.43457 343.3473 67.04004 343.8294 57.23535 344.3115 20.69824 344.7936 5.746094 345.2757 20.22754 345.7578 26.55566 346.2400 31.82617 346.7221 35.62207 347.2042 31.28613 347.6863 15.82031 348.1684 10.39551 348.6505 51.04590 349.1327 109.9932 349.6148 166.7100 350.0969 196.4141 350.5790 202.3789 351.0611 197.9033 351.5432 185.3711 352.0254 167.0996 352.5075 141.0859 352.9896 105.3857 353.4717 81.17188 353.9538 96.24902 354.4359 136.7627 354.9181 174.9199 355.4002 206.2568 355.8823 225.9482 356.3644 226.4727 356.8465 208.1553 357.3286 185.3613 357.8108 165.2148 358.2929 146.6211 358.7750 127.7900 359.2571 95.08691 359.7392 73.20898 360.2213 79.23340 360.7035 111.8818 361.1856 150.7949 361.6677 215.7334 362.1498 268.7686 362.6319 277.9434 363.1140 157.7451 363.5962 69.80078 364.0783 75.69141 364.5604 163.2588 365.0425 243.8164 365.5246 309.7930 366.0067 359.9307 366.4889 388.4639 366.9710 358.2012 367.4531 348.5537 367.9352 381.8193 368.4173 446.1074 368.8994 488.3096 369.3815 478.8389 369.8636 471.8584 370.3458 490.7012 370.8279 549.1729 371.3100 609.4375 371.7921 664.7148 372.2742 723.0117 372.7563 800.6602 373.2385 891.0547 373.7206 1004.673 374.2027 1141.358 374.6848 1296.440 375.1669 1488.553 375.6490 1700.198 376.1312 1964.042 376.6133 2345.514 377.0954 2860.681 377.5775 3440.573 378.0596 4152.354 378.5417 4972.203 379.0239 5492.058 379.5060 5708.584 379.9881 5622.719 380.4702 5128.184 380.9523 4232.228 381.4344 3346.174 381.9166 2556.620 382.3987 1887.089 382.8808 1372.581 383.3629 1020.231 383.8450 771.2500 384.3271 601.7393 384.8093 497.3145 385.2914 419.8311 385.7735 363.8193 386.2556 324.0771 386.7377 289.1025 387.2198 261.3164 387.7020 259.7295 388.1841 342.5625 388.6662 446.2959 389.1483 481.7490 389.6304 399.2920 390.1125 288.9238 390.5947 206.0869 391.0768 147.9199 391.5589 107.4834 392.0410 92.23730 392.5231 86.71973 393.0052 79.11426 393.4874 64.63867 393.9695 54.97559 394.4516 54.00293 394.9337 60.69434 395.4158 73.26367 395.8979 97.43555 396.3801 121.5674 396.8622 137.0801 397.3443 136.1055 397.8264 151.8174 398.3085 211.9131 398.7906 282.4912 399.2728 321.9004 399.7549 288.9482 400.2370 270.4619 400.7191 279.4922 401.2012 316.4775 401.6833 380.4707 402.1655 477.9453 402.6476 595.2959 403.1297 724.9922 403.6118 881.3428 404.0939 1016.809 404.5760 1119.449 405.0582 1195.382 405.5403 1268.695 406.0224 1333.743 406.5045 1408.488 406.9866 1503.413 407.4688 1618.332 407.9509 1757.076 408.4330 1921.786 408.9151 2109.146 409.3972 2304.601 409.8793 2506.970 410.3615 2749.766 410.8436 3049.976 411.3257 3408.601 411.8078 3805.238 412.2899 4228.275 412.7720 4747.295 413.2542 5359.121 413.7363 6112.156 414.2184 7169.598 414.7005 8577.298 415.1826 10331.74 415.6647 12552.17 416.1469 15228.33 416.6290 17939.61 417.1111 21247.60 417.5932 24160.82 418.0753 25296.05 418.5574 23358.24 419.0396 20320.38 419.5217 16611.08 420.0038 12431.25 420.4859 8862.120 420.9680 6468.629 421.4501 4770.164 421.9323 3506.564 422.4144 2788.449 422.8965 2237.340 423.3786 1814.276 423.8607 1510.899 424.3428 1296.556 424.8250 1213.655 425.3071 1178.251 425.7892 1164.030 426.2713 1172.754 426.7534 1196.510 427.2355 1220.463 427.7177 1268.430 428.1998 1383.412 428.6819 1601.711 429.1640 1805.684 429.6461 1976.864 430.1282 2111.602 430.6104 2170.274 431.0925 2149.401 431.5746 2059.837 432.0567 1888.872 432.5388 1633.521 433.0209 1400.206 433.5031 1212.745 433.9852 1060.249 434.4673 918.4678 434.9494 787.8809 435.4315 653.2275 435.9136 479.7197 436.3958 295.4355 436.8779 176.7998 437.3600 145.3232 437.8421 155.3760 438.3242 170.3467 438.8063 188.4141 439.2885 204.1982 439.7706 203.1973 440.2527 205.5107 440.7348 242.5000 441.2169 322.3340 441.6990 373.8916 442.1812 332.0938 442.6633 248.1309 443.1454 182.6328 443.6275 154.8711 444.1096 147.8975 444.5917 166.6777 445.0739 208.3223 445.5560 236.4219 446.0381 233.6436 446.5202 221.9395 447.0023 214.1201 447.4844 204.3223 447.9666 207.0703 448.4487 218.7305 448.9308 243.4756 449.4129 302.0449 449.8950 443.4160 450.3771 536.0518 450.8593 510.1816 451.3413 336.2744 451.8235 222.4902 452.3056 185.7930 452.7877 184.1689 453.2698 152.4863 453.7519 87.28516 454.2340 51.28516 454.7162 81.58203 455.1983 152.0430 455.6804 154.8047 456.1625 86.15820 456.6446 9.542969 457.1267 27.32812 457.6089 30.71484 458.0910 15.84473 458.5731 22.90430 459.0552 62.46582 459.5373 73.49902 460.0194 61.49512 460.5016 44.70312 460.9837 25.63672 461.4658 11.09668 461.9479 11.59570 462.4300 32.45312 462.9121 45.09863 463.3943 26.58496 463.8764 3.353516 464.3585 25.61328 464.8406 31.00195 465.3227 31.69434 465.8048 32.64551 466.2870 33.98535 466.7691 29.40332 467.2512 13.06836 467.7333 6.450195 468.2154 23.98145 468.6975 44.78320 469.1797 56.58984 469.6618 57.02539 470.1439 49.93945 470.6260 48.91113 471.1081 64.79590 471.5902 73.54980 472.0724 60.51270 472.5545 23.44531 473.0366 1.407227 473.5187 3.477539 474.0008 1.028320 474.4829 10.77734 474.9651 24.67383 475.4472 27.52246 475.9293 8.095703 476.4114 20.26660 476.8935 29.82324 477.3756 21.31152 477.8578 6.529297 478.3399 8.257813 478.8220 23.46094 479.3041 41.24512 479.7862 65.79883 480.2683 83.77832 480.7505 74.12500 481.2326 50.54102 481.7147 41.82129 482.1968 84.88086 482.6789 124.7949 483.1610 124.4258 483.6432 74.40039 484.1253 42.90332 484.6074 63.48047 485.0895 100.8633 485.5716 124.6289 486.0537 126.1621 486.5359 120.0215 487.0180 102.7754 487.5001 78.15430 487.9822 63.48242 488.4643 60.30566 488.9464 64.97070 489.4286 78.35840 489.9107 103.5244 490.3928 123.2959 490.8749 141.1162 491.3570 148.0537 491.8391 122.5293 492.3213 65.19141 492.8034 18.67969 493.2855 1.200195 493.7676 0.5078130 494.2497 20.31348 494.7318 57.53809 495.2140 84.82617 495.6961 62.42480 496.1782 18.13672 496.6603 4.020508 497.1424 43.08496 497.6245 86.81738 498.1067 94.37012 498.5888 77.03418 499.0709 61.67188 499.5530 56.45508 500.0351 58.39551 500.5172 67.58008 500.9994 84.47949 501.4815 99.91602 501.9636 115.0391 502.4457 125.3643 502.9278 127.1826 503.4099 105.9824 503.8921 95.05176 504.3742 105.5410 504.8563 129.8906 505.3384 133.2070 505.8205 103.4443 506.3026 77.24023 506.7848 78.31934 507.2669 114.2686 507.7490 123.6367 508.2311 101.5049 508.7132 65.06152 509.1953 28.58691 509.6775 6.380859 510.1596 20.14648 510.6417 6.953125 511.1238 49.87891 511.6059 50.57324 512.0880 12.96387 512.5701 15.02832 513.0522 4.788086 513.5344 35.89551 514.0165 110.2354 514.4986 241.3418 514.9807 337.0000 515.4628 318.3086 515.9449 230.2197 516.4271 148.5020 516.9092 88.22949 517.3913 47.96680 517.8734 32.56836 518.3555 43.09375 518.8376 55.30762 519.3198 85.30566 519.8019 103.2480 520.2840 87.08789 520.7661 0.5830080 521.2482 46.51562 521.7303 36.28516 522.2125 7.691406 522.6946 36.44922 523.1767 49.62988 523.6588 50.06445 524.1409 29.55469 524.6230 6.051758 525.1052 5.877930 525.5873 34.87695 526.0694 71.64551 526.5515 34.87988 527.0336 41.12695 527.5157 51.67871 527.9979 54.72949 528.4800 174.7480 528.9621 197.1084 529.4442 145.6826 529.9263 90.35352 530.4084 53.76758 530.8906 36.44824 531.3727 43.98535 531.8548 79.09570 532.3369 111.6787 532.8190 130.0791 533.3011 144.0850 533.7833 160.6787 534.2654 188.0693 534.7475 200.5186 535.2296 190.5947 535.7117 165.9912 536.1938 152.5439 536.6760 152.9814 537.1581 154.0322 537.6402 148.7725 538.1223 135.9463 538.6044 142.9395 539.0865 178.2012 539.5687 209.2920 540.0508 184.8350 540.5329 114.4404 541.0150 72.52637 541.4971 91.61035 541.9792 131.2139 542.4614 115.3994 542.9435 57.77148 543.4256 21.45215 543.9077 77.68750 544.3898 154.2627 544.8719 174.5771 545.3541 122.5205 545.8362 72.12988 546.3183 57.19434 546.8004 65.21289 547.2825 80.27930 547.7646 111.6807 548.2468 129.0752 548.7289 120.5068 549.2110 92.98242 549.6931 74.01465 550.1752 63.36328 550.6573 59.77148 551.1395 63.41699 551.6216 77.94336 552.1037 108.7061 552.5858 155.7197 553.0679 196.1504 553.5500 194.9717 554.0322 154.2607 554.5143 119.5352 554.9964 101.4854 555.4785 95.14355 555.9606 96.48242 556.4427 103.7637 556.9249 106.3525 557.4070 91.04980 557.8891 71.32910 558.3712 59.46973 558.8533 55.89160 559.3354 67.05176 559.8176 111.4756 560.2997 165.7012 560.7818 206.0703 561.2639 226.4004 561.7460 231.3320 562.2281 211.9346 562.7103 176.6719 563.1924 153.5410 563.6745 134.7256 564.1566 132.7793 564.6387 156.0859 565.1208 208.2197 565.6030 264.0801 566.0851 334.2656 566.5672 383.7061 567.0493 361.8203 567.5314 272.2861 568.0135 202.1807 568.4957 174.0684 568.9778 167.4189 569.4599 144.8926 569.9420 113.8271 570.4241 104.6719 570.9063 162.4395 571.3884 236.0811 571.8705 265.1855 572.3526 247.2500 572.8347 244.6826 573.3168 294.7188 573.7990 371.6807 574.2811 454.3623 574.7632 557.9189 575.2453 640.8252 575.7274 672.5156 576.2095 683.9854 576.6917 741.8584 577.1738 909.9648 577.6559 1018.722 578.1380 1011.794 578.6201 894.9209 579.1022 762.6602 579.5844 612.4814 580.0665 474.4014 580.5486 368.7754 581.0307 292.0557 581.5128 228.1670 581.9949 176.0176 582.4771 132.7109 582.9592 101.9824 583.4413 80.23340 583.9234 55.49121 584.4055 1.108398 584.8876 46.25000 585.3698 24.89062 585.8519 54.21484 586.3340 113.6572 586.8161 111.3291 587.2982 88.52344 587.7803 65.22656 588.2625 37.92676 588.7446 25.97266 589.2267 46.30859 589.7088 71.25098 590.1909 65.24219 590.6730 4.701172 591.1552 18.46484 591.6373 27.29102 592.1194 110.0625 592.6015 125.3691 593.0836 68.62012 593.5657 18.49121 594.0479 28.28223 594.5300 75.61426 595.0121 98.41699 595.4942 94.66797 595.9763 86.68945 596.4584 87.93164 596.9406 97.81543 597.4227 116.5684 597.9048 148.4922 598.3869 181.5498 598.8690 214.8574 599.3511 244.9785 599.8333 266.1104 600.3154 297.7656 600.7975 297.8945 601.2796 238.5107 601.7617 123.1719 602.2438 55.61426 602.7260 57.72363 603.2081 70.68066 603.6902 51.82715 604.1723 3.303711 604.6544 25.67188 605.1365 5.459961 605.6187 28.59277 606.1008 35.55566 606.5829 22.16602 607.0650 18.03418 607.5471 46.51855 608.0292 72.87793 608.5114 32.42773 608.9935 51.19727 609.4756 94.19824 609.9577 2.527344 610.4398 105.0049 610.9219 149.7500 611.4041 115.9873 611.8862 87.84668 612.3683 81.25879 612.8504 86.65723 613.3325 93.99707 613.8146 84.01172 614.2968 123.0234 614.7789 251.0371 615.2610 398.1436 615.7431 405.1230 616.2252 256.4424 616.7073 124.5850 617.1895 76.86914 617.6716 88.46191 618.1537 102.1025 618.6358 116.8516 619.1179 116.4160 619.6000 68.87988 620.0822 9.219727 620.5643 17.79004 621.0464 3.072266 621.5285 23.28027 622.0106 56.23828 622.4927 87.24902 622.9749 106.9229 623.4570 106.0488 623.9391 102.0605 624.4212 81.83691 624.9033 61.46777 625.3854 89.89355 625.8676 197.8701 626.3497 285.3623 626.8318 311.7090 627.3139 283.6309 627.7960 258.6875 628.2781 233.9590 628.7603 236.0361 629.2424 314.2471 629.7245 434.3447 630.2066 502.0986 630.6887 496.5283 631.1708 480.2725 631.6530 506.5820 632.1351 559.1973 632.6172 613.8398 633.0993 657.0576 633.5814 706.7129 634.0635 771.8525 634.5457 847.8916 635.0278 921.0342 635.5099 965.6826 635.9920 1035.259 636.4741 1153.645 636.9562 1325.777 637.4384 1474.681 637.9205 1591.390 638.4026 1714.863 638.8847 1879.732 639.3668 2080.923 639.8489 2278.898 640.3311 2462.322 640.8132 2663.651 641.2953 2940.350 641.7774 3264.592 642.2595 3581.549 642.7416 3879.675 643.2238 4146.135 643.7059 4395.894 644.1880 4609.150 644.6701 4739.174 645.1522 4767.893 645.6343 4702.868 646.1165 4527.762 646.5986 4233.645 647.0807 3943.048 647.5628 3660.754 648.0449 3370.275 648.5270 3050.032 649.0092 2696.338 649.4913 2365.778 649.9734 2053.652 650.4555 1776.122 650.9376 1561.635 651.4197 1399.225 651.9019 1261.600 652.3840 1141.731 652.8661 1038.925 653.3482 960.1816 653.8303 899.1836 654.3124 837.4551 654.7946 755.6680 655.2767 680.1787 655.7588 622.3193 656.2409 582.9980 656.7230 558.9189 657.2051 568.0908 657.6872 571.8350 658.1693 544.3389 658.6514 476.8965 659.1335 419.1270 659.6157 374.0859 660.0978 334.1387 660.5799 282.4316 661.0620 225.0801 661.5441 197.7236 662.0262 218.9424 662.5084 256.6650 662.9905 282.4424 663.4726 296.4482 663.9547 297.1064 664.4368 269.0107 664.9189 239.6201 665.4011 223.1240 665.8832 219.1582 666.3653 219.0576 666.8474 218.5527 667.3295 218.0146 667.8116 229.7129 668.2938 258.5010 668.7759 249.2549 669.2580 188.5352 669.7401 119.1250 670.2222 89.56641 670.7043 96.57910 671.1865 105.4521 671.6686 112.8330 672.1507 113.8877 672.6328 96.51758 673.1149 68.15430 673.5970 46.05078 674.0792 42.50781 674.5613 43.38086 675.0434 31.52344 675.5255 13.66602 676.0076 24.46680 676.4897 120.4023 676.9719 198.6738 677.4540 210.2363 677.9361 146.3848 678.4182 113.4551 678.9003 126.5801 679.3824 143.9883 679.8646 122.5371 680.3467 66.54492 680.8288 35.91211 681.3109 37.33789 681.7930 59.01172 682.2751 107.1602 682.7573 163.3477 683.2394 190.8965 683.7215 161.5508 684.2036 121.3242 684.6857 90.35742 685.1678 68.56055 685.6500 54.73633 686.1321 45.76172 686.6142 49.49805 687.0963 78.23438 687.5784 126.3828 688.0605 140.0215 688.5427 108.7715 689.0248 69.32422 689.5069 41.00586 689.9890 22.72070 690.4711 1.019531 690.9532 31.65625 691.4354 54.65234 691.9175 51.51953 692.3996 33.45898 692.8817 18.58984 693.3638 11.52734 693.8459 4.046875 694.3281 17.05078 694.8102 38.90039 695.2923 44.07422 695.7744 0.7480470 696.2565 23.90820 696.7386 2.966797 697.2208 42.28516 697.7029 58.93945 698.1850 41.00000 698.6671 14.37500 699.1492 20.33594 699.6313 54.41797 700.1135 44.55664 700.5956 6.125000 701.0777 44.66797 701.5598 7.494141 702.0419 48.65234 702.5240 44.83203 703.0062 27.67578 703.4883 94.15430 703.9704 115.1621 704.4525 117.3691 704.9346 122.2168 705.4167 147.6016 705.8989 145.6836 706.3810 90.16211 706.8631 30.37109 707.3452 37.52148 707.8273 126.6777 708.3094 180.5332 708.7916 170.2070 709.2737 129.8828 709.7558 120.1426 710.2379 134.9199 710.7200 149.3848 711.2021 151.0391 711.6843 148.3398 712.1664 153.1719 712.6485 161.2402 713.1306 154.4863 713.6127 95.48242 714.0948 46.88672 714.5770 47.79883 715.0591 102.5684 715.5412 124.8867 716.0233 96.36328 716.5054 67.29883 716.9875 78.15625 717.4697 128.3379 717.9518 155.4824 718.4339 155.3809 718.9160 140.3398 719.3981 105.9902 719.8802 69.24219 720.3624 68.48047 720.8445 130.7988 721.3266 188.0020 721.8087 181.5020 722.2908 148.1855 722.7729 140.9668 723.2551 216.0508 723.7372 262.0156 724.2193 252.5781 724.7014 205.9648 725.1835 169.3145 725.6656 140.5859 726.1478 129.0508 726.6299 144.7168 727.1120 176.3418 727.5941 190.6328 728.0762 188.7324 728.5583 181.9453 729.0405 176.7305 729.5226 171.0059 730.0047 163.5957 730.4868 154.6855 730.9689 142.6797 731.4510 135.1445 731.9332 119.3633 732.4153 83.92969 732.8974 16.60156 733.3795 36.08008 733.8616 85.59961 734.3438 101.7598 734.8259 27.85156 735.3080 133.1152 735.7901 224.0215 736.2722 211.3262 736.7543 164.5137 737.2365 164.9648 737.7186 196.7617 738.2007 227.6836 738.6828 240.5996 739.1649 256.6992 739.6470 289.8711 740.1292 333.7969 740.6113 374.3984 741.0934 401.3945 741.5755 434.4121 742.0576 479.2949 742.5397 532.8477 743.0219 582.3984 743.5040 629.4629 743.9861 663.2891 744.4682 664.9414 744.9503 652.1172 745.4324 680.4746 745.9146 746.3086 746.3967 811.1348 746.8788 850.8105 747.3609 875.9395 747.8430 893.2207 748.3251 902.5957 748.8073 908.4258 749.2894 915.8359 749.7715 919.0312 750.2536 915.1738 750.7357 905.9219 751.2178 881.2793 751.7000 836.5254 752.1821 787.5195 752.6642 747.1094 753.1463 717.0566 753.6284 711.6914 754.1105 741.7227 754.5927 768.8242 755.0748 755.1738 755.5569 710.6582 756.0390 650.8965 756.5211 551.8398 757.0032 472.0586 757.4854 440.8418 757.9675 440.8379 758.4496 428.8438 758.9317 395.7285 759.4138 364.5254 759.8959 337.0312 760.3781 316.6035 760.8602 316.0000 761.3423 331.4551 761.8244 331.3691 762.3065 280.8730 762.7886 215.9512 763.2708 176.0195 763.7529 161.2129 764.2350 169.2871 764.7171 231.1426 765.1992 287.3984 765.6813 295.2832 766.1635 243.2676 766.6456 233.3906 767.1277 290.2988 767.6098 348.5859 768.0919 366.1055 768.5740 343.3770 769.0562 312.3672 769.5383 271.9512 770.0204 238.1641 770.5025 231.0879 770.9846 239.0312 771.4667 243.5840 771.9489 241.5918 772.4310 237.8359 772.9131 232.8691 773.3952 228.3672 773.8773 226.3320 774.3594 237.5723 774.8416 232.8184 775.3237 199.8926 775.8058 163.5332 776.2879 163.5449 776.7700 200.2480 777.2521 224.9668 777.7343 226.1094 778.2164 215.4824 778.6985 208.5312 779.1806 202.7188 779.6627 191.9863 780.1448 150.8008 780.6270 128.1328 781.1091 169.4863 781.5912 247.6348 782.0733 278.7285 782.5554 227.3340 783.0375 177.4219 783.5197 142.5762 784.0018 124.0703 784.4839 135.8086 784.9660 178.7285 785.4481 213.1211 785.9302 216.3965 786.4124 200.1680 786.8945 178.7656 787.3766 153.7832 787.8587 133.3926 788.3408 127.2812 788.8229 123.1973 789.3051 107.7559 789.7872 78.76758 790.2693 86.04883 790.7514 163.4082 791.2335 223.9824 791.7156 205.5840 792.1978 111.8730 792.6799 90.85742 793.1620 144.4727 793.6441 201.6719 794.1262 195.7891 794.6083 158.0645 795.0905 133.4023 795.5726 127.0645 796.0547 125.8828 796.5368 115.6445 797.0189 112.2891 797.5010 132.6797 797.9832 198.5352 798.4653 230.2285 798.9474 212.4199 799.4295 184.5488 799.9116 195.1426 800.3937 239.9473 800.8759 250.0938 801.3580 210.4258 801.8401 167.9434 802.3222 176.0801 802.8043 213.5449 803.2864 251.6914 803.7686 302.5098 804.2507 318.0801 804.7328 243.7871 805.2149 140.8008 805.6970 95.54492 806.1791 135.8535 806.6613 165.8008 807.1434 173.1602 807.6255 166.5547 808.1076 152.2070 808.5897 133.8047 809.0718 138.5527 809.5540 191.4648 810.0361 241.6621 810.5182 230.3828 811.0003 181.3516 811.4824 141.0273 811.9645 118.4434 812.4467 114.5645 812.9288 148.0215 813.4109 197.5156 813.8930 206.4863 814.3751 166.1836 814.8572 122.4004 815.3394 85.29492 815.8215 57.28711 816.3036 43.85352 816.7857 46.08789 817.2678 61.71289 817.7499 104.9863 818.2321 146.6934 818.7142 162.1484 819.1963 154.5859 819.6784 143.9102 820.1605 81.29492 820.6426 83.59375 821.1248 223.3516 821.6068 458.7598 822.0889 508.7188 822.5710 356.5215 823.0532 208.3906 823.5353 167.8301 824.0174 207.7734 824.4995 328.0449 824.9816 503.3965 825.4637 595.4980 825.9459 438.7402 826.4280 256.8906 826.9101 181.1211 827.3922 224.6191 827.8743 231.3867 828.3564 179.3066 828.8386 130.3691 829.3207 117.3223 829.8028 134.0684 830.2849 132.6172 830.7670 113.2246 831.2491 90.84766 831.7313 78.57617 832.2134 68.20508 832.6955 45.35352 833.1776 9.740234 833.6597 12.67969 834.1418 9.033203 834.6240 8.185547 835.1061 38.59766 835.5882 85.81641 836.0703 94.50977 836.5524 54.20508 837.0345 18.21484 837.5167 36.66797 837.9988 89.47852 838.4809 114.5293 838.9630 109.4590 839.4451 100.6602 839.9272 102.7363 840.4094 111.2656 840.8915 123.4902 841.3736 139.6152 841.8557 156.3320 842.3378 177.4395 842.8199 192.6934 843.3021 190.5957 843.7842 169.9590 844.2663 175.1934 844.7484 210.6914 845.2305 233.2148 845.7126 183.4707 846.1948 104.8828 846.6769 51.60156 847.1590 28.10547 847.6411 43.26758 848.1232 161.1582 848.6053 276.9395 849.0875 311.1836 849.5696 236.5332 850.0517 194.1816 850.5338 195.2461 851.0159 199.5469 851.4980 153.5176 851.9802 80.23828 852.4623 69.31055 852.9444 134.2559 853.4265 193.5566 853.9086 170.1523 854.3907 119.4004 854.8729 88.35352 855.3550 84.17578 855.8371 110.6699 856.3192 198.4668 856.8013 277.4766 857.2834 282.3789 857.7656 211.3457 858.2477 172.9766 858.7298 175.0684 859.2119 185.3906 859.6940 179.7676 860.1761 161.2188 860.6583 120.1094 861.1404 42.09961 861.6225 18.43555 862.1046 160.2598 862.5867 313.1660 863.0688 355.5137 863.5510 249.1113 864.0331 182.6875 864.5152 162.5586 864.9973 159.1504 865.4794 147.9688 865.9615 130.5254 866.4437 109.4883 866.9258 84.29297 867.4079 67.33789 867.8900 62.04688 868.3721 71.59570 868.8542 105.4648 869.3364 188.9961 869.8185 222.6211 870.3006 186.6641 870.7827 133.9121 871.2648 106.2461 871.7469 100.6992 872.2291 86.78711 872.7112 62.79492 873.1933 33.90039 873.6754 0.6582030 874.1575 31.95898 874.6396 64.95898 875.1218 104.2598 875.6039 112.4473 876.0860 53.06641 876.5681 15.51953 877.0502 60.95703 877.5323 79.95508 878.0145 101.3867 878.4966 125.2129 878.9787 149.5879 879.4608 182.3984 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